Anion-templated assembly of a supramolecular cage complex
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Ημερομηνία
1998
Συγγραφείς
Elefteria Psillakis
Michael D Ward
Jon A McCleverty
John C Jeffery
Charles‐Antoine Carraz
Karen LV Mann
James S Fleming
Τίτλος Εφημερίδας
Περιοδικό ISSN
Τίτλος τόμου
Εκδότης
Wiley‐vch verlag gmbh
Περίληψη
THe templating effect of the tetrafluoroborate ion leads to assembly of four CoII ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with NiII a simpler dinuclear complex forms.
Περιγραφή
Λέξεις-κλειδιά
Παραπομπή
J. S Fleming, K. LV Mann, C.A.Carraz, E.Psillakis, J. C Jeffery, J. A McCleverty, M.D Ward , "Anion-Templated Assembly of a Supramolecular Cage Complex ",Ang. chem. interna. edit.,vol.37,no.9 ,pp.1279-1281,1998.doi:10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q