Elefteria PsillakisMichael D WardJon A McClevertyJohn C JefferyCharlesâAntoine CarrazKaren LV MannJames S Fleming2024-10-312024-10-3119982015-09-23J. S Fleming, K. LV Mann, C.A.Carraz, E.Psillakis, J. C Jeffery, J. A McCleverty, M.D Ward , "Anion-Templated Assembly of a Supramolecular Cage Complex ",Ang. chem. interna. edit.,vol.37,no.9 ,pp.1279-1281,1998.doi:10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Qhttps://dspace.library.tuc.gr/handle/123456789/1014THe templating effect of the tetrafluoroborate ion leads to assembly of four CoII ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with NiII a simpler dinuclear complex forms.enhttp://creativecommons.org/licenses/by/4.0/Anion-templated assembly of a supramolecular cage complexPeer-Reviewed Journal Publication